852520-79-7

Basic information

• Product Name: 1-{5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-methoxymethoxy-undec-1-yn-4-ol
• Synonyms: 1-{5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-methoxymethoxy-undec-1-yn-4-ol
• CAS NO: 852520-79-7
• Molecular Weight: 506.68
• Mol File: 852520-79-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-{5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-methoxymethoxy-undec-1-yn-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-{5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-methoxymethoxy-undec-1-yn-4-ol(852520-79-7)
• EPA Substance Registry System: 1-{5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-methoxymethoxy-undec-1-yn-4-ol(852520-79-7)

Safety Data

• Hazardous Substances Data: 852520-79-7(Hazardous Substances Data)

Upstream product

• 261954-39-6 (2S,3S)-1-Chlorononane-2,3-diol 
• 850166-83-5 6-(4-methoxybenzyloxy)-hex-2-enoic acid ethyl ester 
• 119649-27-3 4-((4-methoxybenzyl)oxy)butanal 
• 119649-45-5 4-(p-methoxybenzyloxy)butan-1-ol 
• 79605-70-2 (S)-1-[(S)-oxiran-2-yl]heptan-1-ol 
• 2746-25-0 p-Methoxybenzyl bromide 
• 67242-74-4 (E)-1-chloro-2-nonene 
• 5921-73-3 2-nonyn-1-ol 
• 111-25-1 1-bromo-hexane 
• 31502-14-4 2-nonenyl alcohol 
• 852520-71-9 5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid 
• 852520-74-2 4-(2,2-dibromovinyl)-5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolane 
• 852520-70-8 2,3-dihydroxy-6-(4-methoxybenzyloxy)-hexanoic acid ethyl ester 
• 852520-72-0 {5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-methanol 

Downstream Products

• 852520-80-0 tert-butyl-[4-{5-[3-(4-methoxybenzyloxy)-propyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-1-(1-methoxymethoxyheptyl)-but-3-ynyloxy]-dimethylsilane 

Relevant articles and documents

Total synthesis of microcarpalide

An efficient, convergent approach for the total synthesis of microcarpalide (1) is described. The synthetic strategy features the Sharpless asymmetric dihydroxylation, regioselective epoxide opening with various nucleophiles such as a lithium acetylide and cuprates derived from the vinyl stannane and the vinyl iodide for the construction of a C7-C8 trans-double bond and Yamaguchi macrolactonization as the key steps.