85267-90-9

Basic information

• Product Name: 1-Pentanone, 4-methyl-1,3-diphenyl-
• CAS NO: 85267-90-9
• Molecular Formula: C18H20O
• Molecular Weight: 252.356
• Mol File: 85267-90-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-Pentanone, 4-methyl-1,3-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pentanone, 4-methyl-1,3-diphenyl-(85267-90-9)
• EPA Substance Registry System: 1-Pentanone, 4-methyl-1,3-diphenyl-(85267-90-9)

Safety Data

• Hazardous Substances Data: 85267-90-9(Hazardous Substances Data)

Upstream product

• 3262-89-3 triphenylboroxine 
• 36597-08-7 (E)-4-methyl-1-phenyl-2-penten-1-one 
• 1068-55-9 isopropylmagnesium chloride 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 14371-10-9 (E)-3-phenylpropenal 
• 591-51-5 phenyllithium 
• 75-26-3 isopropyl bromide 
• 920-39-8 isopropylmagnesium bromide 
• 94-41-7 benzalacetophenone 
• 32831-01-9 3-chloro-3-phenylpropiophenone 
• 1539-32-8 4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester 
• 611-69-8 rac-2-methyl-1-phenylpropan-1-ol 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 1333501-16-8 2,2,6,6-tetramethyl-1-(2-methyl-1-phenylpropoxy)piperidine 

Relevant articles and documents

Mn-Enabled Radical-Based Alkyl-Alkyl Cross-Coupling Reaction from 4-Alkyl-1,4-dihydropyridines

Highly efficient alkylation of β-chloro ketones and their derivatives was achieved by means of domino dehydrochlorination/Mn-enabled radical-based alkyl-alkyl cross-coupling reaction. In situ-generated α,β-unsaturated ketones and their analogues were identified as the reaction intermediates. Known bioactive compounds, such as melperone and azaperone, could be easily prepared from β-chloropropiophenone in two steps.

Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts

Copper complexes of phosphoramidites efficiently catalyzed asymmetric addition of arylboron reagents to acyclic enones. Importantly, rare 1,4-insertion of arylcopper(I) was identified which led directly to O-bound copper enolates. The new mechanism is fundamentally different from classical oxidative addition/reductive elimination of organocopper(I) on enones.

Chiral Lewis acid catalyzed enantioselective conjugate radical additions to α,β-unsaturated 2-pyridyl ketones

We have investigated the utility of a pyridine-based achiral template in enantioselective conjugate radical additions. Georg Thieme Verlag Stuttgart.