85293-82-9Relevant articles and documents
Small Rings, 85. - Attempts to Synthesize Alkyltri-tert-butyltetrahedranes by the Cyclopentadienone Route; Synthesis of the Cyclopentadienones
Maier, Guenther,Franz, Lothar Hermann
, p. 139 - 146 (2007/10/02)
Starting from 2-bromotri-tert-butylcyclopentadienone (1) a series of highly substituted cyclopentadienones has been prepared, hoping that they might be suitable candidates for the synthesis of a variety of tetrahedranes with different sterically demanding substituents. - Key Words: Nucleophilic addition / Sigmatropic rearrangement / Steric hindrance