85354-75-2

Basic information

• Product Name: [2,2'-imonobis(benzaldehyde) N,N'-dimethyl-N,N'-1,10-phenanthroline-2,9-diylhydrazonato^(1-)bis(pyridine)]cobalt(II) tetrafluoroborate
• CAS NO: 85354-75-2
• Molecular Weight: 992.959
• Mol File: 85354-75-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2,2'-imonobis(benzaldehyde) N,N'-dimethyl-N,N'-1,10-phenanthroline-2,9-diylhydrazonato^(1-)bis(pyridine)]cobalt(II) tetrafluoroborate(CAS DataBase Reference)
• NIST Chemistry Reference: [2,2'-imonobis(benzaldehyde) N,N'-dimethyl-N,N'-1,10-phenanthroline-2,9-diylhydrazonato^(1-)bis(pyridine)]cobalt(II) tetrafluoroborate(85354-75-2)
• EPA Substance Registry System: [2,2'-imonobis(benzaldehyde) N,N'-dimethyl-N,N'-1,10-phenanthroline-2,9-diylhydrazonato^(1-)bis(pyridine)]cobalt(II) tetrafluoroborate(85354-75-2)

Safety Data

• Hazardous Substances Data: 85354-75-2(Hazardous Substances Data)

Upstream product

• 15684-35-2 cobalt(II) tetrafluoroborate hexahydrate 
• 49579-63-7 diphenylamine-2,2′-dicarboxaldehyde 
• 143-66-8 sodium tetraphenyl borate 
• 74339-63-2 2,9-di(L-methylhydrazino)-1,10-phenanthroline 

Relevant articles and documents

Synthesis and X-Ray Structure of a Cobalt(II) Complex of a Negatively Charged Quinquedentate Macrocyclic Ligand

Reaction of 2,2'-iminobisbenzaldehyde with 2,9-di(1-methylhydrazino)-1,10-phenanthroline in the presence of cobalt(II) ions and pyridine leads to the formation of the spin-free title complex(+) (py = pyridine).The X-ray structure of the tetraphenylborate salt confirms a seven-co-ordinate, distored pentagonal-bipyramidal geometry for the metal ion, which is bound equatorially by five nirtogens from the macrocycle and has two pyridine molecules in the axial sites.The complex crystallises in space group P21/n with a = 16.786(4), b = 23.034(4), c = 13.546(3) Angstroem, β = 97.09(3)deg, and Z = 4.The structure was solved by Pat terson and Fourier-difference techniques and refined to R = 0.097 and R' = 0.079 for 2 458 observed reflections.