853654-19-0

Basic information

• Product Name: 1-[4-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-1-methyl-siletane
• Synonyms: 1-[4-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-1-methyl-siletane
• CAS NO: 853654-19-0
• Molecular Weight: 306.596
• Mol File: 853654-19-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[4-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-1-methyl-siletane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[4-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-1-methyl-siletane(853654-19-0)
• EPA Substance Registry System: 1-[4-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-1-methyl-siletane(853654-19-0)

Safety Data

• Hazardous Substances Data: 853654-19-0(Hazardous Substances Data)

Upstream product

• 107556-40-1 <4-<<(tert-butyldimethylsilyl)oxy>methyl>phenyl>magnesium bromide 
• 2351-34-0 1-chloro-1-methylsiletane 

Downstream Products

• 853654-22-5 1-[4-(biphenyl-4-yloxymethyl)-phenyl]-1-methyl-siletane 
• 853654-24-7 1-methyl-1-[4-(3-phenyl-propoxymethyl)-phenyl]-siletane 
• 853654-23-6 1-[4-(4-methoxy-phenoxymethyl)-phenyl]-1-methyl-siletane 
• 853654-25-8 1-methyl-1-[4-(1-phenyl-ethoxymethyl)-phenyl]-siletane 
• 775356-24-6 4-(2-isopropyl-5-methyl-cyclohexyloxymethyl)-phenol 
• 853654-27-0 4-(3-phenyl-propoxymethyl)-phenol 
• 853654-21-4 1-(4-bromomethyl-phenyl)-1-methyl-siletane 
• 853654-28-1 4-(1-phenyl-ethoxymethyl)-phenol 
• 853654-20-3 [4-(1-methyl-siletan-1-yl)-phenyl]-methanol 

Relevant articles and documents

The para-siletanylbenzyl (PSB) ether: A peroxide-cleavable protecting group for alcohols and phenols

A novel arylmethyl protecting group that is electronically similar to benzyl (Bn) but that can be cleaved under mild oxidizing conditions in the presence of para-methoxybenzyl (PMB) is described herein. para-Siletanylbenzyl (PSB) ethers are formed in one or two steps from the corresponding alcohols and cleaved in one or two steps with basic peroxide. Alcohols and phenols have been protected in good yields and deprotected cleanly under mild oxidative conditions.