853748-87-5

Basic information

• Product Name: (S)-non-5-yn-4-ol
• Synonyms: (S)-non-5-yn-4-ol
• CAS NO: 853748-87-5
• Molecular Weight: 140.225
• Mol File: 853748-87-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-non-5-yn-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-non-5-yn-4-ol(853748-87-5)
• EPA Substance Registry System: (S)-non-5-yn-4-ol(853748-87-5)

Safety Data

• Hazardous Substances Data: 853748-87-5(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 14129-46-5 (+/-)-non-5-yn-4-ol 

Downstream Products

• 853748-89-7 (2-butyl-1-o-tolyl-hex-2-enyloxy)-triethyl-silane 
• 853748-93-3 [2-butyl-1-(4-chloro-phenyl)-hex-2-enyloxy]-triethyl-silane 
• 853748-90-0 (2-butyl-1-p-tolyl-hex-2-enyloxy)-triethyl-silane 
• 853748-88-6 (2-butyl-1-phenyl-hex-2-enyloxy)-triethyl-silane 

Relevant articles and documents

Enantioselective and regioselective nickel-catalyzed multicomponent coupling of chiral allenes, aromatic aldehydes, and silanes

A detailed account of the development of a recently developed, nickel-catalyzed multicomponent coupling of chiral allenes, aromatic aldehydes, and silanes is described. The axial chirality of the allene is transferred completely to the product, a trisubstituted Z-allylic alcohol protected as a silyl ether. A very high preference for sp rather than sp2 coupling is observed, and differentially substituted allenes undergo highly site-selective coupling. These transformations represent the first enantioselective multi-component coupling processes of allenes.