85429-54-5

Basic information

• Product Name: Dimethyl-((E)-1-phenyl-but-1-enyl)-amine
• CAS NO: 85429-54-5
• Molecular Weight: 175.274
• Mol File: 85429-54-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dimethyl-((E)-1-phenyl-but-1-enyl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl-((E)-1-phenyl-but-1-enyl)-amine(85429-54-5)
• EPA Substance Registry System: Dimethyl-((E)-1-phenyl-but-1-enyl)-amine(85429-54-5)

Safety Data

• Hazardous Substances Data: 85429-54-5(Hazardous Substances Data)

Upstream product

• 85429-30-7 ((E)-2-Bromo-1-phenyl-vinyl)-dimethyl-amine 
• 75-03-6 ethyl iodide 
• 85429-36-3 C₁₀H₁₂LiN 
• 14548-16-4 Dimethyl-(1-phenyl-vinyl)-amine 

Relevant articles and documents

Enamines β-lithiees. I. Preparations et reactions d'alkylation

The action of alkyllithium reagents on β-bromoenamines 1-9 quickly yields, in THF, β-lithioenamines through halogen - metal exchange.If metallic lithium is used instead of organolithium compounds, β-lithioenamines are also formed but in this case they are accompanied by small amounts of by-products.The action of alkyllithium reagents R1Li on the β-chloroenamine 10 provides a new source of β-lithioenamines in which nucleophilic insertion of the R1 group takes place. β-Lithioenamines are stable compounds even up to 20 deg C in most cases.With alkyl iodides, β-lithioenamines react vigorously even at low temperature.The reaction is stereospecific with retention of configuration.This reaction generates either β-substituted enamines or, by easy acidic hydrolysis, α-substituted carbonyl compounds.The C-alkylation reaction is observed alone.