855272-22-9

Basic information

• Product Name: 4-(2-methylphenyl)-1,6-heptadien-4-ol
• Synonyms: 4-(2-methylphenyl)-1,6-heptadien-4-ol
• CAS NO: 855272-22-9
• Molecular Weight: 202.296
• Mol File: 855272-22-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-(2-methylphenyl)-1,6-heptadien-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(2-methylphenyl)-1,6-heptadien-4-ol(855272-22-9)
• EPA Substance Registry System: 4-(2-methylphenyl)-1,6-heptadien-4-ol(855272-22-9)

Safety Data

• Hazardous Substances Data: 855272-22-9(Hazardous Substances Data)

Upstream product

• 1010106-91-8 1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl o-tolyl ketone 
• 38050-78-1 Allyl-dimethyl-aluminium 
• 89-71-4 2-Methyl-benzoic acid methyl ester 
• 106-95-6 allyl bromide 
• 18854-66-5 tris(allyl)aluminum 
• 95-49-8 2-methylchlorobenzene 
• 1730-25-2 allylmagnesium bromide 

Relevant articles and documents

An efficient of Grignard-type procedure for the preparation of gem-diallylated compound

An efficient and a new procedure for the conversion of various carboxylic acid derivatives into the corresponding gem-diallylated compound under mild reaction condition has been developed. The triallylaluminum mediated Grignard-type addition of carboxylic acid derivative was utilized as a key operation to affect the transformation. The procedure is operationally simple, giving good to excellent product yields for a broad range of substrates. The chemoselectivity and regioselectivity of triallylaluminum were also demonstrated.

Generation of allyl Grignard reagents via titanocene-catalyzed activation of allyl halides

A protocol for the generation of allyl Grignard reagents via the catalytic activation of allyl halides is described herein. Subsequent nucleophilic addition to carbonyl derivatives provided the desired homo allylic alcohols in excellent yields (84-99%). E