85572-58-3

Basic information

• Product Name: 2-Amino-9-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-9H-purin-6-ol
• Synonyms: 2-Amino-9-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-9H-purin-6-ol
• CAS NO: 85572-58-3
• Molecular Weight: 553.618
• Mol File: 85572-58-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Amino-9-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-9H-purin-6-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Amino-9-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-9H-purin-6-ol(85572-58-3)
• EPA Substance Registry System: 2-Amino-9-((2R,3S,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-9H-purin-6-ol(85572-58-3)

Safety Data

• Hazardous Substances Data: 85572-58-3(Hazardous Substances Data)

Upstream product

• 62255-44-1 1-O-acetyl-2,3,5-tris-O-(benzyl)-α, β-D-arabinofuranose 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 52554-29-7 2,3,5-tri-O-benzyl-α- and β-D-arabinofuranosyl chlorides 
• 35085-24-6 2-amino-6-chloro-9-(2,3,5-triphenylmethoxy-β-D-arabinofuranosyl)purine 

Downstream Products

• 38819-10-2 9-β-D-arabinofuranosyl-guanine 

Relevant articles and documents

Stereoselective synthesis of 9-β-d-arabianofuranosyl guanine and 2-amino-9-(β-d-arabianofuranosyl)purine

9-β-d-Arabianofuranosyl guanine (6) and 2-amino-9-(β-d- arabianofuranosyl)purine (8) were prepared from 2-amino-6-chloro-9-(2,3,5- triphenylmethoxyl-β-d-arabianofuranosyl)purine (4), a key intermediate which was stereoselectively prepared from 2,3,5-triphenylmethoxyl-d- arabianofuranose and 2-amino-6-chloro-purine. The yield of the intermediate was obviously improved and only β-isomer was formed by using the activated molecular sieve as environmental friendly catalyst, overcoming the defect that a 1:1 mixture of α- and β-isomers was formed, which was difficult to separate, when toxic mercury cyanide was previously used as catalyst.