85669-64-3

Basic information

• Product Name: Phosphoric acid, diethyl (2Z)-3-phenyl-2-propenyl ester
• CAS NO: 85669-64-3
• Molecular Formula: C13H19O4P
• Molecular Weight: 270.265
• Mol File: 85669-64-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphoric acid, diethyl (2Z)-3-phenyl-2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric acid, diethyl (2Z)-3-phenyl-2-propenyl ester(85669-64-3)
• EPA Substance Registry System: Phosphoric acid, diethyl (2Z)-3-phenyl-2-propenyl ester(85669-64-3)

Safety Data

• Hazardous Substances Data: 85669-64-3(Hazardous Substances Data)

Upstream product

• 1504-58-1 3-Phenyl-2-propyn-1-ol 
• 536-74-3 phenylacetylene 
• 104-54-1 3-Phenylpropenol 
• 814-49-3 diethyl chlorophosphate 
• 4510-34-3 (Z)-cinnamyl alcohol 

Downstream Products

• 1240492-43-6 4,4,5,5-tetramethyl-2-(2-phenylcyclopropyl)-1,3,2-dioxaborolane 
• 151231-67-3 (N-cinnamylimino)triphenylphosphorane 
• 120990-23-0 N-(phenylmethylidene)-N-[(E)-3-phenylprop-2-enyl]amine 
• 120990-24-1 (E)-3-Acetamido-1-phenylprop-1-ene 
• 4335-60-8 (E)-cinnamylamine 
• 20068-20-6 (R)-3-phenyl-1-pentene 
• 43219-51-8 (E)-(3-isocyanoprop-1-en-1-yl)benzene 
• 1620466-04-7 (E)-2-cinnamyl-6-methyl-N-(quinolin-8-yl)benzamide 
• 1620466-51-4 (Z)-2-cinnamyl-6-methyl-N-(quinolin-8-yl)benzamide 
• 57294-86-7 (E)-cinnamyl azide 
• 945684-74-2 (R)-(-)-3-(dimethylphenylsilyl)-3-phenyl-1-propene 

Relevant articles and documents

Copper-Catalyzed Perfluoroalkylation of Allyl Phosphates with Stable Perfluoroalkylzinc Reagents

A general and practical method for copper-catalyzed cross-coupling of allyl phosphates with stable perfluoroalkylzinc reagents has been developed. The reaction proceeds under mild reaction conditions with high efficiency, good functional group tolerance, and high regio- A nd stereoselectivities and provides general, straightforward, and useful access to allyl-perfluoroalkyl compounds. Preliminary mechanistic studies reveal that the allyl copper intermediate may be involved in the catalytic cycle.

Asymmetric synthesis of α-chiral allylic silanes by enantioconvergent γ-selective copper(I)-catalyzed Allylic Silylation

Gamma way: Regio- and enantioselective allylic substitution with a silicon nucleophile generated by copper(I)-catalyzed Si-B bond activation provides direct access to α-chiral allylic silanes from linear acceptors. The enantioconvergent catalysis employing McQuade's six-membered N-heterocyclic-carbene-copper(I) catalyst is applicable to aryl- and alkyl-substituted allylic phosphates (see scheme). Copyright