85710-72-1Relevant articles and documents
Electrooxidative Cleavage of Carbon-Carbon Bonds. 2. Double Cleavage of α,β-Epoxyalkanones and Enantiospecific Syntheses of Chiral Methyl trans- and cis-Chrysanthemates from (+)- and (-)-Carvones
Torii, Sigeru,Inokuchi, Tsutomu,Oi, Ryu
, p. 1944 - 1951 (2007/10/02)
The stereospecific synthesis of chiral methyl trans- and cis-chrysanthemates (1 and 26) from (+)- and (-)-carvones (7a,b) is described.Methyl (3R)- and (3S)-3-(1-chloro-1-methylethyl)-5-oxohexanoates (3) and methyl (3S)- and (3R)-3-(1-chloro-1-methylethyl