857591-32-3

Basic information

• Product Name: 4-methoxy-N-(3-pentyl)aniline
• Synonyms: 4-methoxy-N-(3-pentyl)aniline
• CAS NO: 857591-32-3
• Molecular Weight: 193.289
• Mol File: 857591-32-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 4-methoxy-N-(3-pentyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-N-(3-pentyl)aniline(857591-32-3)
• EPA Substance Registry System: 4-methoxy-N-(3-pentyl)aniline(857591-32-3)

Safety Data

• Hazardous Substances Data: 857591-32-3(Hazardous Substances Data)

Upstream product

• 584-02-1 2-pentanol 
• 104-94-9 4-methoxy-aniline 
• 74-85-1 ethene 
• 5961-59-1 N-methyl-N-(4-methoxyphenyl)amine 
• 781628-30-6 C₁₂H₁₇NO 
• 5470-34-8 4-methoxyformanilide 
• 925-90-6 ethylmagnesium bromide 
• 39031-27-1 4-methoxy-benzaldehyde-(O-carbamoyl oxime ) 
• 3717-21-3 (E)-4-methoxybenzaldoxime 

Relevant articles and documents

Implication of a Silyl Cobalt Dihydride Complex as a Useful Catalyst for the Hydrosilylation of Imines

Here, we describe the formation and use of silyl cobalt (III) dihydride complexes as powerful catalysts for the hydrosilylation of a variety of imines starting from a low-valent well-defined cobalt (I) complex. The reaction is efficient at low catalyst loadings with a diverse range of imines bearing various protecting groups, as well as aliphatic ketimines and quinoline. Kinetics, DFT calculations, NMR spectroscopic studies, deuteration experiments, and X-ray diffraction analyses allowed us to propose a catalytic cycle based on silyl dihydrocobalt (III) complexes performing a hydrocobaltation.

Hydrogen-Borrowing Amination of Secondary Alcohols Promoted by a (Cyclopentadienone)iron Complex

Thanks to a highly active catalyst, the scope of the (cyclopentadienone)iron complex-promoted 'hydrogen-borrowing' (HB) amination has been expanded to secondary alcohols, which had previously been reported to react only in the presence of large amounts of co-catalysts. A range of cyclic and acyclic secondary alcohols were reacted with aromatic and aliphatic amines giving fair to excellent yields of the substitution products. The catalyst was also able to promote the cyclization of diols bearing a secondary alcohol group with primary amines to generate saturated N-heterocycles.

NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines

A general and efficient hydrosilylation of imines catalysed by a well defined NHC-carbene cyclopentadienyl iron complex has been developed. Both aldimines and ketimines are converted to the corresponding amines under mild conditions, and under visible light activation.