85972-28-7

Basic information

• Product Name: Ethanone, 1-(3,4-diiodo-1,3-cyclohexadien-1-yl)-
• CAS NO: 85972-28-7
• Molecular Formula: C8H8I2O
• Molecular Weight: 373.96
• Mol File: 85972-28-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(3,4-diiodo-1,3-cyclohexadien-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(3,4-diiodo-1,3-cyclohexadien-1-yl)-(85972-28-7)
• EPA Substance Registry System: Ethanone, 1-(3,4-diiodo-1,3-cyclohexadien-1-yl)-(85972-28-7)

Safety Data

• Hazardous Substances Data: 85972-28-7(Hazardous Substances Data)

Upstream product

• 85972-20-9 (Z)-1-Chloro-2,3-diiodobutadiene 
• 78-94-4 methyl vinyl ketone 

Downstream Products

• 13329-40-3 4-Iodoacetophenone 

Relevant articles and documents

Preparation and Diels-Alder Reactivity of Several New Chalcogen-Halogen Substituted Butadienes

Addition of halogens and pseudohalogens across one ?-bond of 1,4-dichlorobut-2-yne, followed by a 1,4-elimination, is an efficient synthesis of several new polysubstituted butadienes.If the product dienes have a sulfur or selenium substituent they are quite reactive, undergoing cycloaddition with the moderately reactive dienophile methyl vinyl ketone at 20 deg C in the presence of boron trifluoride etherate.The regiochemistry of the cycloadditions was elucidated, and the limitations of the methodology are discussed.