86001-22-1Relevant articles and documents
Preparation, crystal structures, and properties of new conjugated π-electron systems with 3-guaiazulenyl and 4-(dimethylamino)phenyl groups
Takekuma, Shin-Ichi,Hori, Seiki,Minematsu, Toshie,Takekuma, Hideko
body text, p. 1472 - 1484 (2009/05/06)
Reaction of guaiazulene with l,2-bis[4-(dimethylamino)phenyl]-l,2- ethanediol in methanol in the presence of hydrochloric acid at 60°C for 3h gives l,l-bis[4-(dimethylamino)phenyl]-2-(3-guaiazulenyl)ethylene, in 81% yield, via pinacol rearrangement and fu
Pinacolization and reduction of aromatic carbonyls with aluminium-KOH
Khurana, Jitender M.,Sehgal, Arti,Gogia, Amita,Manian, Aparna,Maikap, Golak C.
, p. 2213 - 2215 (2007/10/03)
A simple and rapid procedure for the pinacolization of aromatic aldehydes and reduction of hindered ketones with inexpensive aluminium and KOH in methanol at ambient temperature is reported. The pinacolization and reduction are proposed to be proceeding via single electron transfer from aluminium. Copyright 1996 by the Royal Society of Chemistry.