86040-06-4Relevant articles and documents
Total syntheses of the resorcylic acid lactones paecilomycin F and cochliomycin C using an intramolecular loh-type α-allylation reaction for macrolide formation
Ma, Xiang,Bolte, Benoit,Banwell, Martin G.,Willis, Anthony C.
supporting information, p. 4226 - 4229 (2016/09/09)
Subjection of the resorcylic ester 16 to a Nozaki-Hiyama-Kishi reaction afforded the 12-membered lactone 17, while treatment of it under the Loh-type α-allylation conditions using indium metal gave the isomeric, 14-membered macrolide 18. Compound 18 was readily elaborated to the resorcylic acid lactone type natural products paecilomycin F and cochliomycin C.
First Stereoselective Synthesis of the Cytotoxic Polyketide (4R)-1-(3,5-Dihydroxyphenyl)-4-hydroxypentan-2-one
Rajendra Prasad, Kothakonda,Purushotham Reddy, Sudina,Suresh Babu, Katragadda,Madhusudana Rao, Janaswamy
, p. 143 - 147 (2015/10/19)
The first stereoselective synthesis of the cytotoxic polyketide (4R)-1-(3,5-dihydroxyphenyl)-4-hydroxypentan-2-one (1) was achieved from readily available propylene oxide and 3,5-dimethoxybenzyl alcohol. The synthesis involves Jacobsen's hydrolytic kinetic resolution (HKR) and Grignard reaction as key steps.
Chiral Building Units from Carbohydrates, VIII. - Syntheses of the Four Isomeric 1,3-Dimethyl-2,9-dioxabicyclononanes
Redlich, Hartmut,Schneider, Bernd,Hoffmann, Reinhard W.,Geueke, Karl-Josef
, p. 393 - 411 (2007/10/02)
Starting from different compounds, the syntheses of the four isomeric bicyclic acetals 17, 32, 36, and 40 - the title compounds - are described.One of these compounds is supposed to direct the attack of the striped ambrosia beetle Trypodendron lineatum Ol
