860648-10-8

Basic information

• Product Name: phenethyl 2,3,4,2',3',4'-O-hexaacetyl-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside
• Synonyms: phenethyl 2,3,4,2',3',4'-O-hexaacetyl-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside
• CAS NO: 860648-10-8
• Molecular Weight: 668.649
• Mol File: 860648-10-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenethyl 2,3,4,2',3',4'-O-hexaacetyl-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenethyl 2,3,4,2',3',4'-O-hexaacetyl-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside(860648-10-8)
• EPA Substance Registry System: phenethyl 2,3,4,2',3',4'-O-hexaacetyl-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside(860648-10-8)

Safety Data

• Hazardous Substances Data: 860648-10-8(Hazardous Substances Data)

Upstream product

• 860648-09-5 phenethyl 2,3,4-tri-O-acetyl-β-D-glucopyranoside 
• 51830-02-5 bromo-2,3,4-O-triacetyl-α/β-L-arabinopyranoside 
• 2280-44-6 D-Glucose 
• 14861-16-6 2-phenylethyl-β-D-glucopyranoside 
• 60-12-8 2-phenylethanol 
• 860648-08-4 phenethyl 2,3,4-tri-O-acetyl-6-O-trityl-β-D-glucopyranoside 
• 860648-07-3 phenethyl 6-O-trityl-β-D-glucopyranoside 

Downstream Products

• 125572-77-2 2-phenylethyl 1-O-α-L-arabinopyranosyl-(1->6)-β-D-glucopyranoside 

Relevant articles and documents

Chemoenzymatic synthesis of naturally occurring phenethyl (1→6)-β-D-gluco-pyranosides

Direct β-glucosidation between phenethyl alcohol and D-glucose (5) using the immobilized β-glucosidase from almonds with the synthetic prepolymer ENTP-4000 gave a phenethyl β-D-glucoside (1) in 34% yield. The coupling of the phenethyl O-β-D-glucopyranoside congener (8) and methylthio-2,3,4-tri-O-acetyl-β-D-xylopyranoside (9), 2,3,4-tri-O-acetyl- α-L-arabinopyranosyl bromide (11), and methylthio 2,3,4-tri-O-acetyl- α-L-rhamnopyranoside (13) afforded the coupled products (10, 12, and 14), respectively. Deprotection of the coupled products (10, 12, and 14) afforded the synthetic phenethyl O-β-D-xylopyranosy-(1→6)- β-D- glucopyranoside (2), phenethyl O-α-L-arabinopyranosy-(1→6)-β-D- glucopyranoside (3), and phenethyl O-α-L-rhamnopyranosy- (1→6)-β-D-glucopyranoside (4), respectively.