860770-58-7Relevant articles and documents
Highly efficient route to o-allylbiaryls via palladium-catalyzed three-component coupling of benzynes, allylic halides, and aryl organometallic reagents
Jayanth, Thiruvellore Thatai,Jeganmohan, Masilamani,Cheng, Chien-Hong
, p. 2921 - 2924 (2005)
(Chemical Equation Presented) o-Allylbiaryl derivatives have been prepared in good to excellent yields by the palladium-catalyzed three-component reaction of allyl halides, benzynes, and aryl organometallic reagents.
Microwave-assisted palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation
Iwasaki, Masayuki,Hayashi, Sayuri,Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
, p. 5200 - 5203 (2008/02/01)
The palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation proceeds at 200-250 °C in a toluene-DMF mixed solvent using microwave heating. Even at such high temperatures, the regio- and stereospecificity of the allyl tr