86143-89-7

Basic information

• Product Name: β,β-dibromovinyl phenyl sulfide
• Synonyms: β,β-dibromovinyl phenyl sulfide
• CAS NO: 86143-89-7
• Molecular Weight: 294.01
• Mol File: 86143-89-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: β,β-dibromovinyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: β,β-dibromovinyl phenyl sulfide(86143-89-7)
• EPA Substance Registry System: β,β-dibromovinyl phenyl sulfide(86143-89-7)

Safety Data

• Hazardous Substances Data: 86143-89-7(Hazardous Substances Data)

Upstream product

• 598-16-3 1,1,2-tribromoethylene 
• 108-98-5 thiophenol 

Downstream Products

• 86143-88-6 β,β-dibromovinyl phenyl sulfone 
• 34097-60-4 methyl benzenesulfonylacetate 
• 86143-90-0 1-phenylsulfonyl-2,2-bis(4-tolylthio)ethene 
• 117644-19-6 1-((Z)-1,2-Dibromo-ethenesulfonyl)-3-nitro-benzene 
• 117644-15-2 1-(2,2-Dibromo-ethenesulfonyl)-3-nitro-benzene 
• 103140-20-1 Z-α,β-dibromovinyl phenyl sulfone 

Relevant articles and documents

NUCLEOPHILIC REACTIONS AT A VINYLIC CENTER. XX. BASE-CATALYZED REARRANGEMENT OF ARYL β,β-DIBROMOVINYL SULFONES TO Z-ARYL α,β-DIBROMOVINYL SULFONES

A series of aryl β,β-dibromovinyl sulfones XC6H4SO2CH=CBr2 were synthesized, and their rearrangement to Z-aryl α,β-dibromovinyl sulfones XC6H4SO2CBr=CHBr by the action of KF.18-crown-6 in benzene was studied.The rearrangement rate increases with increase in the concentration of the base -> and with increase in the electron-withdrawing character of the substituent X and does not depend on the temperature.