861539-91-5Relevant articles and documents
Catalytic aminomethylation of alkenes in a dimethylformamide medium
Karakhanov,Runova,Kardasheva,Losev,Maksimov,Terenina
, p. 179 - 185 (2012)
The hydroaminomethylation of alkenes with dimethylamine catalyzed by rhodium and ruthenium complexes in a dimethylformamide medium under synthesis-gas pressures of 2 MPa has been studied. It has been shown that the combined use of these metals leads to a significant increase in the rate of formation of amines and selectivity for n-alkyldimethylamine. It has been found that the reaction can proceed with dimethylformamide used as an aminating agent without the addition of dimethylamine. Pleiades Publishing, Ltd., 2012.
