861890-42-8

Basic information

• Product Name: ethyl (3R)-3-{[(tert-butoxy)carbonyl]amino}-2-diazo-3-phenylpropanoate
• Synonyms: ethyl (3R)-3-{[(tert-butoxy)carbonyl]amino}-2-diazo-3-phenylpropanoate
• CAS NO: 861890-42-8
• Molecular Weight: 319.36
• Mol File: 861890-42-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (3R)-3-{[(tert-butoxy)carbonyl]amino}-2-diazo-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (3R)-3-{[(tert-butoxy)carbonyl]amino}-2-diazo-3-phenylpropanoate(861890-42-8)
• EPA Substance Registry System: ethyl (3R)-3-{[(tert-butoxy)carbonyl]amino}-2-diazo-3-phenylpropanoate(861890-42-8)

Safety Data

• Hazardous Substances Data: 861890-42-8(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 177896-09-2 tert-butyl benzylidenecarbamate 
• 170947-99-6 C₁₈H₂₁NO₄S 
• 100-52-7 benzaldehyde 
• 150884-50-7 benzaldehyde N-boc imine 

Downstream Products

• 167834-23-3 ethyl (3S)-3-{[(tert-butoxy)carbonyl]amino}-3-phenylpropanoate 

Relevant articles and documents

Silver-Catalyzed Enantioselective Mannich Reaction of Diazoacetate Esters with N-Boc Aldimines

The highly enantioselective Mannich reaction of diazoacetate esters with N-Boc aldimines catalyzed by silver(I) triflate in the presence of (R)-DM-SEGPHOS is reported. The reaction is broad in scope with respect to the (hetero)aromatic aldehyde-derived al