86203-45-4Relevant articles and documents
Syntheses with Aliphatic Dialdehydes, XXXVII. Synthesis, Structure, and Properties of a Decamethinium Cyanine Dye with Indoline End Groups
Reichardt, Christian,Knecht, Josef,Mrosek, Walter,Plaas, Dietrich,Allmann, Rudolf,Kucharczyk, Damian
, p. 1982 - 2000 (2007/10/02)
The reaction of the trisaldehyde trisacetal 4 with 1,3,3-trimethyl-2-methyleneindoline (7) and its tetrafluoroborate 8 yields either the δ-substituted heptamethinium cyanine dye 9 or the decamethinium cyanine dye 10, depending on the reaction conditions.Configuration and conformation of both polymethine dyes have been determined by means of spectroscopic data as well as by X-ray analyses. - The UV/Vis-spectroscopic "trimethine shift" of trinuclear, Y-conjugated, methinylogous guanidinium ions is compared with the "vinylene shift" of dinuclear, linear-conjugated, vinylogous amidinium ions (Table 1).