86227-15-8Relevant articles and documents
Aerobic C?H Hydroxylation by Copper Imine Complexes: The Clip-and-Cleave Concept – Versatility and Limits
Specht, Pascal,Petrillo, Alexander,Becker, Jonathan,Schindler, Siegfried
, p. 1961 - 1970 (2021)
The intramolecular ligand hydroxylation of a series of copper(I) imine complexes during their reaction with dioxygen had been systematically studied. The so-called clip-and-cleave concept offers a facile way to oxygenate aldehydes or ketones. A copper(I)
Synthesis and Crystal Structures of a Series of Amide Copper(II) Complexes
Alilou, El Houssine,Amadei, Edith,Giorgi, Michel,Pierrot, Marcel,Reglier, Marius
, p. 549 - 558 (2007/10/02)
The synthesis and structural determination by X-ray crystallography of four amide copper(II) complexes has been performed: NH(CH2)nPh>(solv)>2 (X = H, solv = H2O, n = 2 1 or 1 2; X = OH, solv = H2O, n = 2 3; solv = MeCN, n = 1 4).In all complexes the co-ordination around the copper atom is a more or less distorted square-based pyramid where the three ligands of the square are unchanged: one oxygen atom of the amide group and two nitrogen atoms of the pyridine nucleus and of the tertiary amine.The fourth ligand is a water molecule (1-3) or an acetonitrile solvent molecule (4).The axial ligand is the oxygen atom of the phenolic group in complexes 3 and 4, while in 1 and 2 this site is occupied by an oxygen atom of a triflate counter ion.
