86272-45-9

Basic information

• Product Name: (S)-2-Benzyloxy-octan-4-ol
• CAS NO: 86272-45-9
• Molecular Weight: 236.354
• Mol File: 86272-45-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-Benzyloxy-octan-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-Benzyloxy-octan-4-ol(86272-45-9)
• EPA Substance Registry System: (S)-2-Benzyloxy-octan-4-ol(86272-45-9)

Safety Data

• Hazardous Substances Data: 86272-45-9(Hazardous Substances Data)

Upstream product

• 1119-90-0 di-n-butylzinc 
• 99032-03-8 (3S)-3-(Benzyloxy)butanal 
• 1920-90-7 tetra-n-butyl lead 
• 90458-77-8 3-(benzyloxy)butanal 

Relevant articles and documents

A new type of complex reagent, R4Pb / TiCl4

Tetraalkllleads (R4Pb) reacted quite smoothly with aldehydes R'CHO in the presence of TiCl4 to produce the corresponding alcohols (RCHOHR′) in high to good yields. The reagent system, R4Pb/ TiCl4, exhibited high chemoselectivity; only aldehydes underwent the alkylation in the presence of ketones. Further, the new reagent exhibited high 1,2- and 1,3-asymmetric induction. The transfer order of alkyl groups in the reaction of aldehydes with mixed tetraalkylleads/TiCl4 was determined; Me>Et.i-Pr?n-Bu.