86289-62-5

Basic information

• Product Name: Acetic acid (3S,4S)-3-methyl-2-oxo-3-phenylsulfanyl-1-oxa-spiro[4.5]dec-4-yl ester
• Synonyms: Acetic acid (3S,4S)-3-methyl-2-oxo-3-phenylsulfanyl-1-oxa-spiro[4.5]dec-4-yl ester
• CAS NO: 86289-62-5
• Molecular Weight: 334.436
• Mol File: 86289-62-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (3S,4S)-3-methyl-2-oxo-3-phenylsulfanyl-1-oxa-spiro[4.5]dec-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (3S,4S)-3-methyl-2-oxo-3-phenylsulfanyl-1-oxa-spiro[4.5]dec-4-yl ester(86289-62-5)
• EPA Substance Registry System: Acetic acid (3S,4S)-3-methyl-2-oxo-3-phenylsulfanyl-1-oxa-spiro[4.5]dec-4-yl ester(86289-62-5)

Safety Data

• Hazardous Substances Data: 86289-62-5(Hazardous Substances Data)

Upstream product

• 94535-33-8 ethyl 2-(phenylthio)propanoate 
• 56037-77-5 1-(acetyloxy)cyclohexanecarboxaldehyde 

Downstream Products

• 86289-76-1 Acetic acid (3S,4S)-3-benzenesulfinyl-3-methyl-2-oxo-1-oxa-spiro[4.5]dec-4-yl ester 
• 86289-67-0 (3S,4S)-4-Hydroxy-3-methyl-3-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one 
• 86289-68-1 (3S,4R)-4-Hydroxy-3-methyl-3-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one 

Relevant articles and documents

Allergenic α-Methylene-γ-butyrolactones. β-Hydroxy-α-methylene-γ-butyrolactones. 2. Syntheses from Ethyl 2-(Phenylthio)propionate and α-Acetoxy Aldehydes

β-Hydroxy-and β-acetoxy-α-methylene-γ-butyrolactones were prepared from α-acetoxy aldehydes and ethyl 2-(phenylthio)propionate.Diastereomeric sulfides 8-11 were separated, oxidized, and thermally eliminated, leading to β-acetoxy-exo-methylene lactones 23-25 and to butenolides 26-28, depending on the configuration of the phenylsulfinyl group. β-Hydroxy lactones 19 were prepared by saponification of the β-acetoxy derivatives.