863118-59-6

Basic information

• Product Name: 2,2'-bis(dichlorophosphino)-4,4'-dimethyl-diphenylether
• Synonyms: 2,2'-bis(dichlorophosphino)-4,4'-dimethyl-diphenylether
• CAS NO: 863118-59-6
• Molecular Weight: 400.008
• Mol File: 863118-59-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,2'-bis(dichlorophosphino)-4,4'-dimethyl-diphenylether(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-bis(dichlorophosphino)-4,4'-dimethyl-diphenylether(863118-59-6)
• EPA Substance Registry System: 2,2'-bis(dichlorophosphino)-4,4'-dimethyl-diphenylether(863118-59-6)

Safety Data

• Hazardous Substances Data: 863118-59-6(Hazardous Substances Data)

Upstream product

• 1579-40-4 1,1'-oxybis(4-methyl-benzene) 

Downstream Products

• 1329705-07-8 2,2'-bis(bis{p-[(diethylamino)methyl]phenyl}phosphino)-4,4'-dimethyldiphenyl ether 
• 863118-61-0 2,2'-bis(bis(2-cyanoethyl)phosphanyl)-4,4'-dimethylphenylether 
• 863118-63-2 2,2'-bis(di-(3,5-di-tert-butyl)phenyl)phosphino-4,4'-dimethyl-diphenylether 
• 882400-32-0 2,2'-bis(phosphino)-4,4'-dimethyl-diphenylether 

Relevant articles and documents

Diphosphine capsules for transition-metal encapsulation

Self-assembly and characterization of novel heterodimeric diphosphine capsules formed by multiple ionic interactions and composed of one tetracationic diphosphine ligand and one complementary tetraanionic calix[4]arene are described. Encapsulation of a palladium atom within a diphosphine capsule is achieved successfully by using the metal complex of the tetracationic diphosphine ligand for the assembly process. In this templated approach to metal encapsulation, the transition-metal complex is an integrated part of the capsule with the transition metal located inside the capsule and is not involved in the assembly process. We present two approaches for capsule assembly by mixing solutions of the precharged building blocks in methanol and mixing solutions of the neutral building blocks in methanol. The scope of the diphosphine capsules and the metallodiphosphine capsules is easily extended by applying tetracationic diphosphine ligands with different backbones (ethylene, diphenyl ether, and xanthene) and cationic binding motifs (p-C6H 4-CH2-ammonium, m-C6H4-ammonium, and m-C6H4-guanidinium). These tetracationic building blocks with different flexibilities and shapes readily associate into capsules with the proper capsular structure, as is indicated by 1H NMR spectroscopy, 1D NOESY, ESI-MS, and modeling studies. Copyright