86341-38-0

Basic information

• Product Name: crotyl-1,4-dimethoxybenzene
• CAS NO: 86341-38-0
• Molecular Weight: 192.258
• Mol File: 86341-38-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: crotyl-1,4-dimethoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: crotyl-1,4-dimethoxybenzene(86341-38-0)
• EPA Substance Registry System: crotyl-1,4-dimethoxybenzene(86341-38-0)

Safety Data

• Hazardous Substances Data: 86341-38-0(Hazardous Substances Data)

Upstream product

• 18292-28-9 1-(trimethylsilyl)but-2-ene 
• 150-78-7 1,4-dimethoxybezene 
• 147249-35-2 (+/-)-1-(2,5-Dimethoxyphenyl)butan-3-ol 
• 93-02-7 2,5-dimethoxybenzaldehyde 
• 118709-30-1 trans-1-(2,5-dimethoxyphenyl)-2-buten-3-one 
• 182132-20-3 Toluene-4-sulfonic acid 3-(2,5-dimethoxy-phenyl)-1-methyl-propyl ester 

Relevant articles and documents

High pressure nucleophilic fluoride-ion substitution reactions: Formation of fluoroalkylbenzenes

A series of 1-phenyl-2-tosyloxy- and 1-phenyl-3-tosyloxyalkanes was synthesized and then subjected to tetrabutylammonium fluoride in THF under 15 kbar (1.5 GPa), 8 kbar or 1 bar pressures. The resultant substitution and elimination reaction product distributions were analyzed. The application of pressure enhanced the progress of the fluoride-ion substitution reactions. The degree of selectivity of the one reaction over the other was found to be a function of tosylate substrate structure and the amount of pressure applied. The exclusive formation of fluoroalkanes from 1-phenyl-2-tosyloxyalkane substrates under 15 kbar pressure demonstrated the potential of the pressure method for prospective use in fluorine-18 radiolabelling applications.

Umpolung of reactivity of allylsilane, allylgermane, and allylstannane via their reaction with thallium(III) salt: A new allylation reaction for aromatic compounds

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