86358-19-2Relevant articles and documents
ELECTROCHEMICAL SYNTHESIS OF PERFLUOROALKYLACETONES
Vol'pin, I. M.,Kurykin, M. A.,Grinberg, V. A.,Vasil'ev, Yu. B.,German, L. S.
, p. 1395 - 1400 (2007/10/02)
The interaction of electrochemically generated radicals in the electrolysis of the perfluorocarboxylic acids RFCF2COOH (I), where RF = F (a), CF3 (b), C2F5 (c), C3F7 (d), C5F11 (e). and C7F15 (f), with isoprenyl acetate (II) was studied.The dependence of the results of the electrolysis on the adsorption capacity of the anode permits the proposition that the interaction of (II) with the ECG-radicals occurs close to the surface of the electrode.The yield of the perfluoroalkylacetones comprised 30-37percent.
Annelation d'enamines par les cetones α,β-ethyleniques fluorees. VI (1): Reaction d'aromatisation
Molines, Huguette,Tordeux, Marc,Wakselman, Claude
, p. 367 - 368 (2007/10/02)
Various perfluoroalkylacetones were prepared by addition of perfluoroalkyliodides to 2-methoxypropene and condensed with 1-pyrrolidinocyclopentene or -cyclohexene.An annelation-aromatisation process led to 4-perfluoroalkyl-6-pyrrolidinoindanes and 1-perfluoroalkyl-3-pyrrolidino-5,6,7,8-tetrahydronaphthalenes.