86404-08-2Relevant articles and documents
ASCORBIC ACID-RELATED COMPOUND AND ANTI-PLANT-VIRUS AGENT
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, (2015/09/22)
The present invention provides a compound represented by formula (1) (wherein each of X1 and X2 independently represents -OR1, -NR2R3 or -CR4R5R6 or the like, each of
Regio- and Chemoselective Alkylation of L-Ascorbic Acid under Mitsunobu Conditions
Tahir, Hasan,Hindsgaul, Ole
, p. 911 - 913 (2007/10/03)
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Organoalane-mediated isomerization of ascorbic and isoascorbic acid derivatives
Schachtner, Josef,Stachel, Hans-Dietrich
, p. 3263 - 3276 (2007/10/03)
Derivatives of L-ascorbic acid 2a, 10a/11a and D-isoascorbic acid 2b, 10b/11b, when treated with triisobutylaluminium, partly epimerize to give the corresponding derivatives of L-isoascorbic acid ent-2b, ent-10b or D-ascorbic acid ent-2a, ent-10a, ent-11a, respectively. Complete removal of the protecting groups is effected by hydrogenolysis of the benzylidene acetals ent-10 and ent-11a. This reaction leads to D-ascorbic acid ent-1a or L-isoascorbic acid ent-1b, respectively. Furthermore, the four acetonides 2 were converted by ozonolysis, transesterification and finally catalytic hydrogenation to the threonic and erythronic acid ketals 9. Copyright (C) Elsevier Science Ltd.