86409-42-9

Basic information

• Product Name: HRu3(μ3-η3-C(OMe)C(Ph)CH)(CO)9
• CAS NO: 86409-42-9
• Molecular Weight: 701.492
• Mol File: 86409-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: HRu3(μ3-η3-C(OMe)C(Ph)CH)(CO)9(CAS DataBase Reference)
• NIST Chemistry Reference: HRu3(μ3-η3-C(OMe)C(Ph)CH)(CO)9(86409-42-9)
• EPA Substance Registry System: HRu3(μ3-η3-C(OMe)C(Ph)CH)(CO)9(86409-42-9)

Safety Data

• Hazardous Substances Data: 86409-42-9(Hazardous Substances Data)

Upstream product

• 71562-47-5 H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Alkylidyne-alkyne coupling on triruthenium clusters. A potential model for Fischer-Tropsch chain growth

The clusters H3Ru3(μ3-CX)(CO)9 (X = OMe, Me, Ph) react with alkynes C2R2 to form the corresponding alkene C2H2R2 and HRu3(μ3-η3-CXCRCR)(CO)9. Terminal alkynes yield mixtures of the two possible isomers in ratios dependent upon the steric bulk of the substituent. Hydrogenation of HRu3(μ3-η3-C(OMe)CRCR)(CO)9 yields the corresponding H3Ru3(μ3-CCHRCH2R)(CO) 9.