86409-85-0

Basic information

• Product Name: Benzene, 1-methyl-4-[[2-(phenylseleno)-1-decenyl]sulfonyl]-, (E)-
• CAS NO: 86409-85-0
• Molecular Formula: C23H30O2SSe
• Molecular Weight: 449.516
• Mol File: 86409-85-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[[2-(phenylseleno)-1-decenyl]sulfonyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[[2-(phenylseleno)-1-decenyl]sulfonyl]-, (E)-(86409-85-0)
• EPA Substance Registry System: Benzene, 1-methyl-4-[[2-(phenylseleno)-1-decenyl]sulfonyl]-, (E)-(86409-85-0)

Safety Data

• Hazardous Substances Data: 86409-85-0(Hazardous Substances Data)

Upstream product

• 764-93-2 1-decyne 
• 68819-94-3 p-tolyl benzeneselenosulfonate 

Downstream Products

• 112389-82-9 1-Methyl-4-(trideca-1,4,5-triene-4-sulfonyl)-benzene 
• 108817-53-4 (E)-3-methoxy-2-n-octyl-1-(p-tolylsulfonyl)-1,3-butadiene 
• 86409-91-8 1-(Dec-1-yne-1-sulfonyl)-4-methyl-benzene 
• 86410-09-5 1-(Toluene-4-sulfonyl)-decan-2-one 
• 86409-98-5 C₂₃H₃₀O₃SSe 
• 122471-78-7 1-Methyl-4-((Z)-2-phenylselanyl-dec-2-ene-1-sulfonyl)-benzene 
• 66606-03-9 n-decyl p-tolyl sulfone 
• 122471-90-3 1-(Dodeca-3,4-diene-3-sulfonyl)-4-methyl-benzene 
• 112389-81-8 1-Methyl-4-(undeca-2,3-diene-2-sulfonyl)-benzene 
• 112389-80-7 1-(Dec-2-yne-1-sulfonyl)-4-methyl-benzene 
• 112389-77-2 1-(Deca-1,2-diene-1-sulfonyl)-4-methyl-benzene 
• 60186-80-3 5-tridecyne 
• 122471-92-5 ((Z)-1-Butyl-non-1-enylselanyl)-benzene 
• 60186-79-0 4-tridecyne 

Relevant articles and documents

Selenosulfonation of Acetylenes: Preparation of Novel β-(Phenylseleno)vinyl Sulfones and Their Conversion to Acetylenic and β-Functionalized Sulfones

The 1,2-additions of Se-phenyl p-tolueneselenosulfonate (1) to acetylenes under mild conditions afford β-(phenylseleno)vinyl sulfones 3, generally in high yields.The reaction is highly regioselective (anti-Markovnikov) and stereoselective (anti) and proceeds via a free-radical chain mechanism initiated by the thermolysis of the selenosulfonate.The oxidation of β-(phenylseleno)vinyl sulfones with m-chloroperbenzoic acid generates the corresponding selenoxides 4, which undergo syn or base-catalyzed elimination to furnish acetylenic sulfones 5.Base-catalyzed alcoholyses of selenoxides 4 in methanol or ethylene glycol produce β-keto sulfone ketals 8 or 10, respectively.Free β-keto sulfones 11 are formed by the acid-catalyzed hydrolysis of the corresponding β-(phenylseleno)vinyl sulfones 3.