864294-75-7Relevant articles and documents
A new multicomponent reaction for direct synthesis of primary γ-nitroamides
Montes D'Oca, Caroline R.,Da Silva, Jessica C.,Guedes, Esthefani P.,Montes D'Oca, Marcelo G.,Santos, Leonardo S.,Nachtigall, Fabiane M.,Russowsky, Dennis
, p. 98427 - 98433 (2016)
A new multicomponent reaction for direct synthesis of γ-nitroamides promoted by ammonium carbonate was developed. A series of γ-nitroamides were synthesized in 35-93% yield from Meldrum's acid, aromatic or aliphatic aldehydes, nitromethane and ammonium carbonate. A mechanistic pathway was proposed based on electrospray ionization mass spectrometry (ESI/MS) experiments.
Conjugate addition nitro-Mannich reaction of carbon and heteroatom nucleophiles to nitroalkenes
Anderson, James C.,Kalogirou, Andreas S.,Tizzard, Graham J.
, p. 9337 - 9351 (2015/03/05)
The conjugate addition nitro-Mannich reactions of ethyl-β-nitroacrylate (1) and β-nitrostyrene (2) with electron rich aromatic nucleophiles, stabilized carbanions, alcohols, amines, thiols, and diphenyl phosphine oxide were investigated. The one pot conju
Michael addition of nitromethane to isopropylidene 5-alkylidenemalonates
Li, Jing-Hua,Li, Zu-Guang,Chen, Qing-Guang
, p. 758 - 759 (2007/10/03)
The nitroethyl derivatives of isopropylidene malonate 2, which were unknown, are synthesised by way of Michael addition of nitromethane to isopropylidene 5-alkylidenemalonates, among them 2,2-dimethyl-5-[1-(nitromethyl) cyclohexyl]-1, 3-dioxane-4,6-dione
