864685-86-9

Basic information

• Product Name: pentamethylcyclopentadienyl titanium chloride (OCH(CH₃)CH₂NC₆H₅)
• Synonyms: pentamethylcyclopentadienyl titanium chloride (OCH(CH₃)CH₂NC₆H₅)
• CAS NO: 864685-86-9
• Molecular Weight: 367.755
• Mol File: 864685-86-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pentamethylcyclopentadienyl titanium chloride (OCH(CH₃)CH₂NC₆H₅)(CAS DataBase Reference)
• NIST Chemistry Reference: pentamethylcyclopentadienyl titanium chloride (OCH(CH₃)CH₂NC₆H₅)(864685-86-9)
• EPA Substance Registry System: pentamethylcyclopentadienyl titanium chloride (OCH(CH₃)CH₂NC₆H₅)(864685-86-9)

Safety Data

• Hazardous Substances Data: 864685-86-9(Hazardous Substances Data)

Upstream product

• 12129-06-5 Cp*TiCl₃ 
• 3233-06-5 1-anilino-propan-2-ol 

Relevant articles and documents

Synthesis and styrene polymerization behavior of new titanium complexes Cp*TiCl(OCHRCH2NAr)

A series of titanium complexes Cp*TiCl(OCHRCH2NAr) (Cp* = C5Me5, R = H, Ar = phenyl (2a); R = H, Ar = 2,6-dimethylphenyl (2b); R = Me, Ar = phenyl (2c); R = Me, Ar = 2,6-dimethylphenyl (2d)) was prepared by the reaction of corresponding 2-phenylamino-ethanol derivatives with Cp*TiCl3 in the presence of excessive triethylamine. All the titanium complexes display higher catalytic activity towards the syndiospecific polymerization of styrene in the presence of modified methylaluminoxane (MMAO) as a cocatalyst, yielding higher molecular weight polystyrenes with higher syndiotacticities and melting temperatures (Tm) than their mother complex Cp*TiCl3. When 2-(2,6-diisopropyl-phenylamino)-ethanol was reacted with Cp*TiCl 3, an unexpected monodentate complex Cp*TiCl 2(OCH2CH2NHC6H3 iPr2-2,6) 3 was obtained. The complex 3 displays relative low catalytic activity towards styrene polymerization, but produces higher molecular weight polystyrene with higher syndiotacticities.