86537-61-3

Basic information

• Product Name: ethyl (2E)-3-phenylprop-2-en-1-yl carbonate
• CAS NO: 86537-61-3
• Molecular Formula: C₁₂H₁₄O₃
• Molecular Weight: 206.2378
• Mol File: 86537-61-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 300.1°C at 760 mmHg
• Flash Point: 113.9°C
• Density: 1.086g/cm³
• Vapor Pressure: 0.00115mmHg at 25°C
• Refractive Index: 1.54
• CAS DataBase Reference: ethyl (2E)-3-phenylprop-2-en-1-yl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2E)-3-phenylprop-2-en-1-yl carbonate(86537-61-3)
• EPA Substance Registry System: ethyl (2E)-3-phenylprop-2-en-1-yl carbonate(86537-61-3)

Safety Data

• Hazardous Substances Data: 86537-61-3(Hazardous Substances Data)

Upstream product

• 104-54-1 3-Phenylpropenol 
• 541-41-3 chloroformic acid ethyl ester 
• 105-58-8 Diethyl carbonate 

Downstream Products

• 134038-43-0 (S)-1-((Z)-(S)-2-Nitro-5-phenyl-pent-4-enoyl)-pyrrolidine-2-carboxylic acid ethyl ester 
• 134038-44-1 (S)-1-((Z)-(R)-2-Nitro-5-phenyl-pent-4-enoyl)-pyrrolidine-2-carboxylic acid ethyl ester 
• 122571-00-0 [(E)-1-(Benzhydrylidene-amino)-4-phenyl-but-3-enyl]-phosphonic acid diethyl ester 
• 5629-57-2 ethyl cinnamate 
• 103550-82-9 (E)-2-(Benzhydrylidene-amino)-5-phenyl-pent-4-enoic acid methyl ester 
• 103550-81-8 2-(Benzhydrylidene-amino)-3-phenyl-pent-4-enoic acid methyl ester 
• 102492-86-4 (E)-4-Methyl-4-nitro-1-phenyl-undec-1-en-5-one 
• 102492-84-2 (E)-5-Nitro-8-phenyl-5-propyl-oct-7-en-4-one 
• 102492-82-0 (E)-4-Ethyl-4-nitro-1-phenyl-non-1-en-5-one 
• 119825-57-9 ethyl 2(4-chlorobenzylidene)amino-2-methyl-5-phenyl-3-pentenoate 
• 119825-58-0 ethyl 2(4-chlorobenzylidene)amino-2-methyl-3-phenyl-4-pentenoate 
• 79918-53-9 ethyl 2-ethyl-2-nitro-5-phenyl-4-pentenoate 
• 104-54-1 3-Phenylpropenol 

Relevant articles and documents

Immobilization of 1,5,7-triazabicyclo[4.4.0]dec-5-ene on magnetic γ-Fe2O3 nanoparticles: A highly recyclable and efficient nanocatalyst for the synthesis of organic carbonates

1,5,7-Triazabicyclo[4.4.0]dec-5-ene was immobilized on magnetic γ-Fe2O3 nanoparticles as a magnetic nanocatalyst. The nanoparticle reagent was obtained with good loading levels and has been successfully used for the efficient and selective synthesis of organic carbonates by the direct condensation of alcohols and diethyl carbonate. The catalyst is quantitatively recovered by an external magnet and can be reused for six cycles with almost consistent activity. 1,5,7-Triazabicyclo[4.4.0]dec-5-ene was immobilized on magnetic γ-Fe2O3 nanoparticles as a magnetic nanocatalyst. The nanoparticle reagent was obtained with good loading levels and has been successfully used for the efficient and selective synthesis of organic carbonates by the direct condensation of alcohols and diethyl carbonate.

Allylic activation across an Ir-Sn heterobimetallic catalyst: Nucleophilic substitution and disproportionation of allylic alcohol

A nucleophilic substitution of allylic alcohols with carbon (arene, heteroarene, allyltrimethylsilane, and 1,3-dicarbonyl compound), sulfur (thiol), oxygen (alcohol), and nitrogen (sulfonamide) nucleophiles has been demonstrated using an in house developed [Ir(COD)(SnCl3)l(μ-Cl)]2 heterobimetallic catalyst in 1,2-dichloroethane to afford the corresponding allylic products in moderate to excellent yields. In 4-hydroxycoumarin, allylation occurs at the 3-position. The diaryl-substituted allylic alcohols undergo disproportionation in presence of the heterobimetallic catalyst to provide the corresponding alkenes and chalcones. An electrophilic mechanism is proposed from Hammett correlation study.