86558-53-4

Basic information

• Product Name: Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1
• Synonyms: Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1
• CAS NO: 86558-53-4
• Molecular Weight: 212.332
• Mol File: 86558-53-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1(86558-53-4)
• EPA Substance Registry System: Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1(86558-53-4)

Safety Data

• Hazardous Substances Data: 86558-53-4(Hazardous Substances Data)

Upstream product

• 41613-59-6 1-ethynyl-2,2,6-trimethyl-1-cyclohexanol 
• 472-66-2 (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 86558-54-5 (Z)-1-(β-methoxyvinyl)-2,6,6-trimethylcyclohexene 
• 86558-55-6 2-<(E)-(β-methoxyvinyl)>-1,3,3-trimethylcyclohexene 
• 86558-56-7 (3R,8aS)-3-Methoxy-5,5,8a-trimethyl-3,5,6,7,8,8a-hexahydro-naphthalene-1,2-dicarboxylic acid dimethyl ester 
• 71558-02-6 Dimethoxy carbonyl-1,2 trimethyl-5,5,8a Octahydro-1,4,4a,5,6,7,8,8a naphtalene-(1RS, 4aSR, 8aRS) 

Relevant articles and documents

SYNTHESE TOTALE DU (+/-)POLIGODIAL, DE LA DRIMENINE ET DE COMPOSES APPARENTES A JONCTION DE CYCLE cis ET trans

Isomerization by base under kinetic or thermodynamic control of the Diels-Alder adduct of 1,3,3-trimethyl-2-vinyl-1-cyclohexene with dimethyl acetylene dicarboxylate leads to two isomers which, after catalytic hydrogenation, give in high yield starting materials for synthesis of trans and cis drimanes.A short total synthesis of (+/-)-polygodial and (+/-)-drimenine from one of these isomers is desribed.