86631-57-4

Basic information

• Product Name: 4-((1S,2R)-2-Hydroxy-1-methyl-2-phenyl-ethyl)-4-methyl-4,5-dihydro-3H-4-azonia-cyclohepta[2,1-a;3,4-a']dinaphthalene; bromide
• Synonyms: 4-((1S,2R)-2-Hydroxy-1-methyl-2-phenyl-ethyl)-4-methyl-4,5-dihydro-3H-4-azonia-cyclohepta[2,1-a;3,4-a']dinaphthalene; bromide
• CAS NO: 86631-57-4
• Molecular Weight: 524.5
• Mol File: 86631-57-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-((1S,2R)-2-Hydroxy-1-methyl-2-phenyl-ethyl)-4-methyl-4,5-dihydro-3H-4-azonia-cyclohepta[2,1-a;3,4-a']dinaphthalene; bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-((1S,2R)-2-Hydroxy-1-methyl-2-phenyl-ethyl)-4-methyl-4,5-dihydro-3H-4-azonia-cyclohepta[2,1-a;3,4-a']dinaphthalene; bromide(86631-57-4)
• EPA Substance Registry System: 4-((1S,2R)-2-Hydroxy-1-methyl-2-phenyl-ethyl)-4-methyl-4,5-dihydro-3H-4-azonia-cyclohepta[2,1-a;3,4-a']dinaphthalene; bromide(86631-57-4)

Safety Data

• Hazardous Substances Data: 86631-57-4(Hazardous Substances Data)

Upstream product

• 299-42-3 ephedrine 
• 86631-56-3 (R)-2,2'-dibromomethyl-1,1'-binaphthalene 
• 54130-90-4 2,2'-di(bromomethyl)-1,1'-binaphthalene 

Downstream Products

• 143971-08-8 (S,1S,2R)-2-azido-2'-<methyl>-1,1'-binaphthyl 
• 19634-89-0 (R)-2,2'-dimethyl-1,1'-binaphthyl 
• 97781-24-3 (1R,2S)-2-[Methyl-(2'-methyl-[1,1']binaphthalenyl-2-ylmethyl)-amino]-1-phenyl-propan-1-ol 

Relevant articles and documents

New and Improved Synthesis of Optically Pure (R)- and (S)-2,2'-Dimethyl-1,1'-binaphthyl and Related Compounds

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METHODE SIMPLE DE SYNTHESE D'AGENTS DE TRANSFERT CHIRAUX PAR ACTION D'UN AGENT ALKYLANT A SQUELETTE BINAPHTYLE-1,1'

A general way for introducing axial chirality in phase transfer catalysts, by quaternarization with 2,2'-bis(bromomethyl)-1,1'-binaphtyl, is described and applied to l(-) ephedrine.One of the resulting catalysts gives 37 percent ee in epoxydation of chalcone.