86632-82-8

Basic information

• Product Name: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol
• Synonyms: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol
• CAS NO: 86632-82-8
• Molecular Weight: 202.251
• Mol File: 86632-82-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol(86632-82-8)
• EPA Substance Registry System: 3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol(86632-82-8)

Safety Data

• Hazardous Substances Data: 86632-82-8(Hazardous Substances Data)

Upstream product

• 135456-78-9 (Z)-(3S,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-3,4,5-trimethoxy-1-trimethylsilanyl-hex-1-ene 
• 135456-77-8 (3S,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-3,4,5-trimethoxy-1-trimethylsilanyl-hex-1-yne 
• 135456-76-7 tert-Butyl-((2S,3R,4S)-6,6-dibromo-2,3,4-trimethoxy-hex-5-enyloxy)-dimethyl-silane 
• 135456-74-5 ((2S,3S,4R)-5,5-Bis-ethylsulfanyl-2,3,4-trimethoxy-pentyloxy)-tert-butyl-dimethyl-silane 
• 135456-75-6 (2R,3S,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,3,4-trimethoxy-pentanal 
• 135456-80-3 (Z)-(2R,3R,4S)-2,3,4-Trimethoxy-6-trimethylsilanyl-hex-5-enal 
• 135456-79-0 (Z)-(2S,3R,4S)-2,3,4-Trimethoxy-6-trimethylsilanyl-hex-5-en-1-ol 
• 135456-73-4 O²,O³,O⁴-trimethyl-L-arabinose diethyl dithioacetal 
• 125459-21-4 2,3-dihydroxy-1,4-dimethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene 
• 125546-17-0 1,4-dimethoxy-1β,4β,4aβ,9α,9aβ,10α-hexahydro-9,10<1',2'>benzenoanthracene 
• 135456-81-4 (1R,4S,5R,6S)-4,5,6-Trimethoxy-cyclohex-2-enol 
• 74-88-4 methyl iodide 
• 86632-81-7 C₂₄H₂₈O₅ 
• 125459-22-5 1,2,3,4-tetramethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene 

Downstream Products

• 130824-36-1 2α,3β,4β,5α-tetramethoxycyclohex-1α-yl 3',5'-dinitrobenzoate 
• 130824-37-2 2β,3β,4α-trimethoxycyclohex-1α-yl 3',5'-dinitrobenzoate 
• 130824-39-4 1α,2α,3β-trimethoxycyclohex-5b-yl 3',5'-dinitrobenzoate 
• 488-73-3 (+/-)-cyclohexane-1r,2c,3t,4c,5t-pentaol 
• 488-73-3 (1α,2β,3α,4α,5β)-1,2,3,4,5-Cyclohexanpentol 
• 130824-38-3 (1R,2S,3R,4S)-2,3,4-Trimethoxy-cyclohexanol 
• 130824-40-7 (3R,5R)-3,4,5-Trimethoxy-cyclohexanol 
• 130824-35-0 proto-quercitol tetramethyl ether 

Relevant articles and documents

An Approach to Total Synthesis of (+)-Lycoricidine

A convergent synthesis of a protected version of (+)-lycoricidine has been accomplished in 13 steps from L-arabinose.Preparation of the aminocyclitol moiety 50 employed a novel vinylsilane-terminated N-sulfonyliminium ion cyclization of vinylsilane aldehyde 42.Closure of the B-ring using an intramolecular Heck reaction afforded lycoricidine derivative 58.An unexpected cyclization of vinylsilane aldehyde 42 allowed for the stereodivergent preparation of semiprotected conduritols 43 and 45.

AN IMPROVED SYNTHESIS OF CONDURITOL A

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