86678-42-4Relevant articles and documents
45. Total Synthesis of (+/-)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage
Oppolzer, Wolfgang,Zutterman, Freddy,Baettig, Kurt
, p. 522 - 533 (2007/10/02)
(+/-)-α-Acoradiene (4) has been synthesized from 3-methoxy-2-cyclohexenone by a sequence of 8 steps.The key steps (Scheme 6) are the regio- and stereoselective photoaddition 7 -> 6 and the reductive fragmentation 6 -> 5.