867338-63-4Relevant articles and documents
Cucurbit[6]uril as a potential catalyst for the acidic decomposition of azidoaminoalkanes
Wieland, Marcel,Mieusset, Jean-Luc,Brinker, Udo H.
experimental part, p. 4351 - 4353 (2012/10/08)
Five azidoalkyl-1-amines and p-azidoaniline have been synthesized and complexed with cucurbit[6]uril in acidic solutions. Isothermal titration calorimetry has been employed to determine the association constant K and the enthalpy of complex formation ΔH of the azidoalkyl- and azidoarylamines. 4-Azidobutyl-1-amine forms by far the most stable complex. Cucurbit[6]uril significantly catalyzes the decomposition of the azidoalkyl- and azidoarylamines studied.