86763-30-6

Basic information

• Product Name: Benzenecarbothioic acid, S-dodecyl ester
• CAS NO: 86763-30-6
• Molecular Formula: C19H30OS
• Molecular Weight: 306.513
• Mol File: 86763-30-6.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, S-dodecyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, S-dodecyl ester(86763-30-6)
• EPA Substance Registry System: Benzenecarbothioic acid, S-dodecyl ester(86763-30-6)

Safety Data

• Hazardous Substances Data: 86763-30-6(Hazardous Substances Data)

Upstream product

• 65-85-0 benzoic acid 
• 112-55-0 1-dodecylthiol 
• 591-50-4 iodobenzene 
• 201230-82-2 carbon monoxide 
• 26960-77-0 sodium dodecanethiolate 
• 24003-11-0 2,4,6-trichlorophenyl benzoate 
• 455-32-3 benzoyl fluoride 
• 50978-45-5 3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide 
• 780-69-8 triethoxyphenylsilane 
• 25477-07-0 n-dodecyl thiosulfate, sodium 
• 143-15-7 1-dodecylbromide 
• 93-97-0 benzoic acid anhydride 
• 20025-90-5 p-dodecylbenzenethiol 
• 100-52-7 benzaldehyde 

Downstream Products

• 100-52-7 benzaldehyde 
• 2469-45-6 didodecyl sulfide 
• 112-55-0 1-dodecylthiol 

Relevant articles and documents

Tunable aryl imidazolium recyclable ionic liquid with dual br?nsted-lewis acid as green catalyst for friedel-crafts acylation and thioesterification

Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling.

One-pot synthesis of thioesters with sodium thiosulfate as a sulfur surrogate under transition metal-free conditions

In this paper, we report an efficient synthetic method for thioester formation from sodium thiosulfate pentahydrate, organic halides, and aryl anhydrides. In the one-pot two-step reactions developed in this study, sodium thiosulfate was used as the sulfur surrogate for acylation with anhydrides, followed by substitution with organic halides through the in situ generation of thioaroylate. Furthermore, two important organic compounds could be successfully synthesized using our developed method. The advantages of the one-pot two-step reactions are operational simplicity, structurally diverse products with 42%-90% yields, use of relatively low toxic and odourless reagents, and easy applicability to large-scale operation.

Ligand-Controlled Divergent Cross-Coupling Involving Organosilicon Compounds for Thioether and Thioester Synthesis

A divergent cross-coupling for both thioether and thioester construction from organosilicon compounds has been developed. Predominant selectivity for Hiyama-type coupling and C1 insertion reaction was achieved under the guidance of ligands. Thioether was obtained under ligand-free conditions in which disulfide generated from homocoupling could be prevented. Meanwhile, application of bidentate phosphine ligands under carbon monoxide atmosphere (CO balloon) afforded the thioester with little decomposition, which was revealed through interval NMR tracking.