86809-02-1

Basic information

• Product Name: methylphenylhydrazone of ethyl trifluoroacetoacetate
• CAS NO: 86809-02-1
• Molecular Weight: 288.27
• Mol File: 86809-02-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methylphenylhydrazone of ethyl trifluoroacetoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methylphenylhydrazone of ethyl trifluoroacetoacetate(86809-02-1)
• EPA Substance Registry System: methylphenylhydrazone of ethyl trifluoroacetoacetate(86809-02-1)

Safety Data

• Hazardous Substances Data: 86809-02-1(Hazardous Substances Data)

Upstream product

• 618-40-6 1-Methyl-1-phenylhydrazine 
• 372-31-6 ethyl 4,4,4-trifluoroacetoacetate 

Relevant articles and documents

TAUTOMERIZATION OF N,N-DISUBSTITUTED HYDRAZONES OF FLUORINE-CONTAINING β-DICARBONYL COMPOUNDS

A PMR study was carried out on the tautomeric equilibrium of N,N-disubstituted hydrazones of β-dicarbonyl compounds bearing a terminal trifluoromethyl group.The introduction of an α-alkyl substituent to disubstituted hydrazones of β-ketoesters shifts the equilibrium toward the imine form while an increase in the bulk of the substituents at the second nitrogen atom slightly favors the enamine form.The fraction of the imine tautomer in methylarylhydrazones of trifluoroacetylpinacolin decreases with the introduction of electron-withdrawing substituents into the aromatic ring.