868170-35-8

Basic information

• Product Name: [silver(I)(PPh₃)2(H₂-trimercaptotriazine)]
• CAS NO: 868170-35-8
• Molecular Weight: 808.717
• Mol File: 868170-35-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [silver(I)(PPh₃)2(H₂-trimercaptotriazine)](CAS DataBase Reference)
• NIST Chemistry Reference: [silver(I)(PPh₃)2(H₂-trimercaptotriazine)](868170-35-8)
• EPA Substance Registry System: [silver(I)(PPh₃)2(H₂-trimercaptotriazine)](868170-35-8)

Safety Data

• Hazardous Substances Data: 868170-35-8(Hazardous Substances Data)

Upstream product

• 86859-00-9 bis(triphenylphosphine)silver(I) nitrate 
• 638-16-4 trithiocyanuric acid 

Relevant articles and documents

Synthesis, crystal structure and luminescence of [Ag(PPh3) 2(H2TMT)]

The silver complex Ag(PPh3)2(H2TMT) (1)(H3TMT = 2,4,6-trimercapto-1,3,5-triazine) has been synthesized and characterized. The ligand trimercaptotriazine exhibits a novel coordination mode and the complex shows a special hydrogen bonding linkage in the crystal packing. The colorless crystals of 1 exhibit broad emission in the visible region at room temperature. TDDFT calculation indicated that the π-π attraction is crucial for fluorescence of the title complex.