868743-79-7

Basic information

• Product Name: tris(2-chlorosulfenyl-1-phenyl-1,3-butanedionato)chromium(III)
• CAS NO: 868743-79-7
• Molecular Weight: 735.07
• Mol File: 868743-79-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris(2-chlorosulfenyl-1-phenyl-1,3-butanedionato)chromium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: tris(2-chlorosulfenyl-1-phenyl-1,3-butanedionato)chromium(III)(868743-79-7)
• EPA Substance Registry System: tris(2-chlorosulfenyl-1-phenyl-1,3-butanedionato)chromium(III)(868743-79-7)

Safety Data

• Hazardous Substances Data: 868743-79-7(Hazardous Substances Data)

Upstream product

• 10545-99-0 sulfur dichloride 

Relevant articles and documents

Reaction of sulfur chlorides with metal β-diketonates

Metal β-diketonates react with sulfur dichloride to form sulfenyl chlorides irrespective of β-substituent. Bulky phenyl and tert-butyl groups do not prevent formation of fully substituted complexes. The possibility of preparing sulfenyl chloride derivatives of rhodium, ruthenium, and vanadium β-diketonates was demonstrated. A new procedure was suggested for preparing chlorosulfenyl-substituted β-diketonates. Disulfur dichloride reacts with metal chelates with the substitution of both chlorine atoms and formation of polynuclear complexes in which the diketonate groups are linked by disulfide bridges. 2005 Pleiades Publishing, Inc.