86941-23-3

Basic information

• Product Name: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyl)-6-methyl-cyclohexanone
• Synonyms: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyl)-6-methyl-cyclohexanone
• CAS NO: 86941-23-3
• Molecular Weight: 248.409
• Mol File: 86941-23-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyl)-6-methyl-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyl)-6-methyl-cyclohexanone(86941-23-3)
• EPA Substance Registry System: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyl)-6-methyl-cyclohexanone(86941-23-3)

Safety Data

• Hazardous Substances Data: 86941-23-3(Hazardous Substances Data)

Upstream product

• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 583-60-8 2-Methylcyclohexanone 
• 141-12-8 neryl acetate 
• 41294-51-3 (C₄H₉)3SnO(C₆H₈CH₃) 
• 13670-83-2 6-methylcyclohexanone lithium enolate 
• 82167-45-1 C₁₃H₂₆BO^(1-)*K⁽¹⁺⁾ 
• 86901-71-5 C₇H₁₁O^(1-)*Cl^(1-)*Zn⁽²⁺⁾ 

Relevant articles and documents

HIGHLY REGIOSELECTIVE GENERATION OF "THERMODYNAMIC" ENOLATES AND THEIR DIRECT CHARACTERIZATION BY NMR

Addition of 2-methylcyclohexanone to 1.05 equiv of KH suspended in THF, followed by treatment with 1.25 equiv of BEt3 gives potassium enoxyborate 2a as a 90-95percent regioisomerically pure species, as judged by its 1H and 13C NMR as well as by GLC analysis of the silylated products, while the use of KN(SiMe3)2 in place of KH gives 1a as a 90-95percent pure substance.The KH-BEt3 procedure also gives 4 and 5 as 91 and 85percent regiochemically pure species, respectively.