869563-31-5

Basic information

• Product Name: C₁₃H₁₆O₂
• Synonyms: C₁₃H₁₆O₂
• CAS NO: 869563-31-5
• Molecular Weight: 204.269
• Mol File: 869563-31-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₆O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₆O₂(869563-31-5)
• EPA Substance Registry System: C₁₃H₁₆O₂(869563-31-5)

Safety Data

• Hazardous Substances Data: 869563-31-5(Hazardous Substances Data)

Upstream product

• 17488-65-2 4-phenylbut-3-en-2-ol 
• 123-62-6 propionic acid anhydride 

Relevant articles and documents

A highly selective ferrocene-based planar chiral PIP (Fc-PIP) acyl transfer catalyst for the kinetic resolution of alcohols

Novel planar chiral ferrocene nucleophilic catalysts (Fc-PIP) containing both central and planar chiral elements were designed and synthesized for catalytic enantioselective acyl transfer of secondary alcohols. A remarkably efficient catalyst with high selectivity factors (up to S = 1892) was identified. Comparing the combination of central and planar chirality revealed a strong requirement for the "matched" chiral elements, indicating that the stereogenic center of the imidazole rings should present itself on the same face as the ferrocenyl fragment; otherwise, the catalyst is completely inactive. An exclusively stacked transition state that accounts for the high selectivity of the kinetic resolution of secondary alcohols is proposed. Notably, this newly designed catalyst family is suitable for the catalytic kinetic resolution of bulky arylalkyl carbinols, producing esters with extremely high ee (>99%).