86984-18-1Relevant articles and documents
Nickel-catalyzed Addition or Coupling Reactions of Grignard Reagents with Halopyrimidines
Elmoghayar, Mohamed R. H.,Groth, Per,Undheim, Kjell
, p. 109 - 114 (2007/10/02)
Phenylmagnesium bromide with NiCl2(dppp) catalysis adds selectively to the unsubstituted position in 2,4-dichlro-5-chloro(fluoro)pyrimidine.X-Ray structure analysis of the hydrolyzed adduct shows an infinite chain by N1 - N3' hydrogen bonding.The hydrolyz