87097-49-2

Basic information

• Product Name: cobalt(II)(INAP)2
• CAS NO: 87097-49-2
• Molecular Weight: 355.275
• Mol File: 87097-49-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cobalt(II)(INAP)2(CAS DataBase Reference)
• NIST Chemistry Reference: cobalt(II)(INAP)2(87097-49-2)
• EPA Substance Registry System: cobalt(II)(INAP)2(87097-49-2)

Safety Data

• Hazardous Substances Data: 87097-49-2(Hazardous Substances Data)

Upstream product

• 6147-53-1 cobalt(II) diacetate tetrahydrate 
• 20597-98-2 iso-nitrosoacetophenone sodium salt 

Relevant articles and documents

Bis- and Tris-chelates of Cobalt with Some Isonitrosoacetophenones

Cobalt complexes of the type, ML2.nH2O , ML2.HL and ML3 have been prepared and characterized.The IR data suggest N- and O-bondings of the oximino group in one and the same molecule of the complex, the exception being 4-NO2 substituted complex where bonding occurs through isonitroso nitrogen only.Substitution in the phenyl ring of the complexes produces shifts in ν(C=O) which are related to the Hammett's substituents parameters.The magnetic moments observed for the cobalt(II) complexes, except that of 4-NO2 substituted complex, indicate distorted octahedral geometry.The PMR spectra of cobalt(III) chelates with 4-MeHINAP and 4-OMeHINAP suggest a cis octahedral structure for these complexes.