871558-39-3

Basic information

• Product Name: [N(2-(P(CHMe₂)2-4-methylphenyl)2^(1-)](Ti=CDBu-t)(C₆D₅)
• Synonyms: [N(2-(P(CHMe₂)2-4-methylphenyl)2^(1-)](Ti=CDBu-t)(C₆D₅)
• CAS NO: 871558-39-3
• Molecular Weight: 629.63
• Mol File: 871558-39-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [N(2-(P(CHMe₂)2-4-methylphenyl)2^(1-)](Ti=CDBu-t)(C₆D₅)(CAS DataBase Reference)
• NIST Chemistry Reference: [N(2-(P(CHMe₂)2-4-methylphenyl)2^(1-)](Ti=CDBu-t)(C₆D₅)(871558-39-3)
• EPA Substance Registry System: [N(2-(P(CHMe₂)2-4-methylphenyl)2^(1-)](Ti=CDBu-t)(C₆D₅)(871558-39-3)

Safety Data

• Hazardous Substances Data: 871558-39-3(Hazardous Substances Data)

Upstream product

• 1076-43-3 benzene-d6 

Relevant articles and documents

Intermolecular C-H bond activation promoted by a titanium alkylidyne

The transient titanium alkylidyne complex (PNP)Ti≡CtBu (PNP = N-[2-P(CHMe2)2-4-methylphenyl]2-), prepared from α-hydrogen abstraction of the corresponding alkylidene-alkyl species (PNP)Ti=CHtBu(CH2tBu), can readily undergo intermolecular 1,2-addition of C-H bonds of benzene and SiMe4. Synthesis and reactivity, isotopic labeling, kinetics, and theoretical studies strongly favor an alkylidyne pathway and the α-H abstraction step to be the rate-determining step. Copyright