87172-82-5

Basic information

• Product Name: Butanedioic acid, 2-(benzoyloxy)-3-hydroxy-, (2R,3R)-
• CAS NO: 87172-82-5
• Molecular Formula: C11H10O7
• Molecular Weight: 254.196
• Mol File: 87172-82-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Butanedioic acid, 2-(benzoyloxy)-3-hydroxy-, (2R,3R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanedioic acid, 2-(benzoyloxy)-3-hydroxy-, (2R,3R)-(87172-82-5)
• EPA Substance Registry System: Butanedioic acid, 2-(benzoyloxy)-3-hydroxy-, (2R,3R)-(87172-82-5)

Safety Data

• Hazardous Substances Data: 87172-82-5(Hazardous Substances Data)

Upstream product

• 87-69-4 L-Tartaric acid 
• 98-88-4 benzoyl chloride 
• 158732-35-5 (R,R)-1,2-bis(benzyloxycarbonyl)-2-hydroxyethyl benzoate 

Downstream Products

• 862155-30-4 (2R,3R)-2-Benzoyloxy-3-(6-{(2R,3R)-2-benzoyloxy-3-[5-((1R,2R)-2-benzoyloxy-1,2-bis-benzyloxycarbonyl-ethoxycarbonyl)-pentylcarbamoyl]-3-hydroxy-propionylamino}-hexanoyloxy)-succinic acid dibenzyl ester 
• 100675-53-4 O-benzoyl-L-tartaric anhydride 
• 1240196-63-7 2-methoxyethyl O-benzoyltartrate 
• 1293914-22-3 C₁₉H₁₅BO₈ 
• 1293914-23-4 C₁₇H₁₂BFO₇ 

Relevant articles and documents

Tartaric acid and its acyl derivatives. Part 5. Direct synthesis of monoacyltartaric acids and novel mono(benzoyl)tartaric anhydride: Unusual findings in tartaric acid acylation

Practical acylation of unprotected tartaric acid 1 by acyl chlorides to the corresponding monoacyltartaric acids 2 has been shown. Several unusual cases in the acylation of 1 are observed; it has been found that two routes of acylation are possible. In the benzoylation of 1, in addition to the expected products, the formation of a previously undescribed monobenzoyltartaric anhydride 7a is reported. An unusual DME cleavage during the course of acylation was also observed. ARKAT USA, Inc.

Use of 1,3-dioxin-4-ones and related compounds in synthesis. XLIV. Asymmetric aldol reaction of 4-trimethylsiloxy-6-methylene-1,3-dioxines: Use of tartaric acid-derived (acyloxy)borane complex as the catalyst

A novel enantioselective synthesis of 1,3-dioxin-4-ones having a 2-hydroxylated alkyl group at the 6-position has been accomplished by chiral tartaric acid-derived acylborane-mediated aldol condensation of the silyl enol ether derived from 6-methyl-derivatives of 1,3-dioxin-4-one with achiral aldehydes.