87202-38-8

Basic information

• Product Name: 1,3-Dodecanedione, 1-phenyl-
• CAS NO: 87202-38-8
• Molecular Formula: C18H26O2
• Molecular Weight: 274.403
• Mol File: 87202-38-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-Dodecanedione, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dodecanedione, 1-phenyl-(87202-38-8)
• EPA Substance Registry System: 1,3-Dodecanedione, 1-phenyl-(87202-38-8)

Safety Data

• Hazardous Substances Data: 87202-38-8(Hazardous Substances Data)

Upstream product

• 111-83-1 1-bromo-octane 
• 93-91-4 1-phenylbutan-1,3-dione 
• 112-12-9 methyl nonyl ketone 
• 93-89-0 benzoic acid ethyl ester 
• 110-42-9 Methyl decanoate 
• 98-86-2 acetophenone 

Downstream Products

• 162470-59-9 2-methyl-1-phenyl-1,3-dodecanedione 

Relevant articles and documents

A New Method for the Construction of α-Diazoketones

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Enantioselective borohydride reduction catalyzed by optically active cobalt complexes

The highly enantioselective borohydride reduction of aromatic ketones or imines to the corresponding alcohols was developed in the presence of a catalytic amount of an optically active cobalt(II) complex catalyst. This enantioselective reduction is carried out using a precisely premodified borohydride with alcohols such as tetrahydrofurfuryl alcohol, ethanol and methanol. High optical yields are obtained by choosing the appropriate alcohol as modifiers and a suitable β-ketoiminato ligand of the catalyst. The enantioselective borohydride reduction has been successfully applied to the preparation of optically active 1,3-diols, the stereoselective reduction of diacylferrocenes, and dynamic and/or kinetic resolution of 1,3-dicarbonyl compounds.