873070-80-5

Basic information

• Product Name: p-tolyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside
• Synonyms: p-tolyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside
• CAS NO: 873070-80-5
• Molecular Weight: 374.458
• Mol File: 873070-80-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: p-tolyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: p-tolyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside(873070-80-5)
• EPA Substance Registry System: p-tolyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside(873070-80-5)

Safety Data

• Hazardous Substances Data: 873070-80-5(Hazardous Substances Data)

Upstream product

• 1152-39-2 p-methylphenyl-1-thio-β-D-galactopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 28244-94-2 4-methylphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside 
• 4163-60-4 β-D-galactose peracetate 
• 106-45-6 para-thiocresol 

Downstream Products

• 873070-82-7 p-tolyl-2,3-di-O-benzoyl-4,6-O-[(R)-1-methoxycarbonylethylidene]-1-thio-β-D-galactopyranoside 
• 620172-07-8 p-methoxyphenyl 2,3-di-O-benzoyl-1-thio-β-D-galactopyranoside 

Relevant articles and documents

Sulfonated Lewis X trisaccharide and synthesis method and application thereof

The invention relates to sulfonated Lewis X trisaccharide having the following structural formula as described in the description, wherein R1 is selected from a hydrogen atom, an alpha- or beta-configuration serine residue, an alpha- or beta-configuration

FeCl3 mediated arylidenation of carbohydrates

Glycosides and thioglycosides based on monosaccharides in reaction with benzaldehyde dimethylacetal or p-methoxybenzaldehyde dimethyl acetal undergo FeCl3-catalyzed (20 mol %) regioselective 4,6-O-arylidenation producing the corresponding acetals in high yields. FeCl3 also mediates acetalation of glycosides and thioglycosides of cellobiose, maltose, and lactose affording the corresponding 4′,6′-O-benzylidene acetals, which were isolated after their acetylation in situ with acetic anhydride and pyridine. The combined yields (two steps) of these final products are also high (61-84%). The procedure is applicable to a wide variety of functional groups including -OBn.